Environmental matrices effect in butyltin determinations by GC/MS

Authors

  • Italo B. Castro Universidade Federal de São Paulo http://orcid.org/0000-0001-8303-5150
  • Patrícia G Costa Universidade Federal do Rio Grande
  • Ednei Gilberto Primel Universidade Federal do Rio Grande
  • Gilberto Fillmann Universidade Federal do Rio Grande

DOI:

https://doi.org/10.5132/eec.2015.01.08

Abstract

The present study evaluated the matrix effect associated to determination of butyltin compounds (tripropyltin (TPrT), tributyltin (TBT), dibutyltin (DBT) and monobutyltin (MBT)) in sediment and mussel tissues using derivatization by Grignard reaction and quantification by gas chromatography coupled mass spectrometry (GC-MS). A non-negligible matrix effect was verified for sediments (54.2, 20.3, 13.6 and -53.6 %) and mussel tissues (-12.5, -32.0, 59.4 and 65.7 %) for TPrT, TBT, DBT and MBT respectively. However, this matrix effect was prevailed by preparing the analytical curves using standard addition techniques. Thus, an analytical method was optimized and validated for a more accurate and precise determination of butyltin compounds in sediment and mussel tissue samples.

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Author Biography

Italo B. Castro, Universidade Federal de São Paulo

Possui graduação em Ciências Biológicas pela Universidade Federal do Ceará (2003), mestrado em Ciências Marinhas Tropicais pelo Instituto de Ciências do Mar (2005) e doutorado em Oceanografia pela Universidade Federal do Rio Grande (2011). Atualmente é membro efetivo do SETAC-BRASIL e pesquisador colaborador das instituições onde cursou mestrado e doutorado. Tem experiência na área de Oceanografia, com ênfase em Oceanografia Biológica e Química, atuando principalmente nos seguintes temas: impactos produzidos pela contaminação marinha por compostos biocidas utilizados em tintas antiincrustrantes, bioindicadores da contaminação marinha e ecotoxicologia marinha.

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Published

17-12-2015

How to Cite

Castro, I. B., Costa, P. G., Primel, E. G., & Fillmann, G. (2015). Environmental matrices effect in butyltin determinations by GC/MS. Ecotoxicology and Environmental Contamination, 10(1), 47–53. https://doi.org/10.5132/eec.2015.01.08

Issue

Vol. 10 No. 1 (2015)

Section

Original Articles

License

Copyright © 2006 ECOTOX-Brasil

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